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Published March 15, 1983 | Published
Journal Article Open

Comparison of quantal, classical, and semiclassical behavior at an isolated avoided crossing

Abstract

The quantal and classical/semiclassical behavior at an isloated avoided crossing are compared. While the quantum mechanical eigenvalue perturbation parameter plots exhibit the avoided crossing, the corresponding primitive semiclassical eigenvalue plots pass through the intersection. Otherwise, the eigenvalues agree well with the quantum mechanical values. The semiclassical splitting at the intersection is calculated from an appropriate Fourier transform. In the quasiperiodic regime, a quantum state near an avoided crossing is seen to exhibit typically more delocalization than the classical state. However, trajectories near the ''separatrix'' display a quasiperiodic ''transition'' between two zeroth order classical states.

Additional Information

© 1983 American Institute of Physics. Received 8 September 1982; accepted 21 October 1982. We are pleased to acknowledge the support of the present research by the U.S. Department of Energy under contract W-7405-eng-26 with the Union Carbide Corporation (at Oak Ridge) and by a grant from the National Science Foundation (at the California Institute of Technology).

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August 19, 2023
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