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Published 1966 | public
Journal Article

Nuclear magnetic resonance spectra of ferrocenyl carbonium ions

Abstract

Recently it has been suggested (1) that the properties of ɑ-metallocenyl carbonium ions can be best explained in terms of mesomeric ring effects not involving metal participation (2). The Ware and Traylor interpretation (1) suggests Ib as the major mesomeric form contributing to the resonance stabilization of the ion I, whereas the metal participation concept (2) envisages the contribution from Ic as the major stabilizing factor.

Additional Information

© 1966 Pergamon Press Ltd. Received 11 February 1966, Available online 8 March 2001. We should like to thank Mrs. R. Stanaszek of the Abbott Laboratories for taking some n. m. r. spectra, the U. S. Public Health Service (Grant No. 5F1 GM 21, 655) for a predoctoral fellowship to one of us (J. J. Dannenberg), the National Science Foundation for support of the research (NSF G24995) at the California Institute of Technology, and the Air Force Materials Laboratory, Research and Technology Division, AFSC, European Office of Aerospace Research, United States Air Force for support of the research [Contract No. AF 61(052)-752] at the Technion-Israel Institute of Technology.

Additional details

Created:
August 19, 2023
Modified:
October 23, 2023