Published October 1960
| public
Journal Article
Protonation of metallocenes by strong acids. Structure of the cation
Chicago
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Abstract
Ferrocene recently has been shown to form a stable complex salt of composition (C_(10_H_(10)Fe•HAlCl_4) in the presence of aluminum chloride and hydrogen chloride. This finding, together with the suggestion that the transition state for electrophilic substitution of ferrocene, ruthenocene and osmocene may involve initial interaction of the electrophile with the metal atom, prompted us to examine then.m.r. spectra of these moetallcenes in media of high acidity.
Additional Information
© 1960 American Chemical Society. Received August 10, 1960. This research was supported by grants from the National Science Foundation and the National Institutes of Health (RG-5978-C1). Contribution No. 2610, Caltech Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena, California.Additional details
- Eprint ID
- 57054
- Resolver ID
- CaltechAUTHORS:20150428-140300077
- NSF
- NIH
- RG-5978-C1
- Created
-
2015-04-28Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2610