Published 1997
| public
Book Section - Chapter
Solvent Dynamics and RRKM Theory of Clusters
- Creators
-
Marcus, R. A.
Abstract
In this chapter we consider the problem of reaction rates in clusters (microcanonical) modified by solvent dynamics. The field is a relatively new one, both experimentally and theoretically, and stems from recent work on well-defined clusters. We first review some theories and results for the solvent dynamics of reactions in constant-temperature condensed-phase systems and then describe two papers from our recent work on the adaptation to microcanonical systems. In the process we comment on a number of questions in the constant-temperature studies and consider the relation of those studies to corresponding future studies of clusters.
Additional Information
© 1997 John Wiley & Sons, Inc. It is a pleasure to acknowledge the support of this research by the National Science Foundation and the Office of Naval Research.Additional details
- Eprint ID
- 56804
- Resolver ID
- CaltechAUTHORS:20150421-093424183
- NSF
- Office of Naval Research (ONR)
- Created
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2015-04-21Created from EPrint's datestamp field
- Updated
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2019-11-22Created from EPrint's last_modified field
- Series Name
- Advances in chemical physics
- Series Volume or Issue Number
- 101