Published March 27, 2009
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Beyond the Historical Perspective on Hydrogen and Electron Transfers
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Marcus, Rudolph A.
Chicago
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Abstract
A brief overview of proton and electron transfer history is given, and various features influencing enzymatic catalysis are discussed. Examples of generic behavior are considered, together with questions that can be addressed for both experimental and computational results. Examples of high and low pre-exponential factors A of the intrinsic rate constant k_H ranging from ~10^(17) s^(-1) to ~10^4 s^(-1) and normal (~10^(13)) are noted with significant error bars and discussed.
Additional Information
© 2009 Royal Society of Chemistry. Many authors have made major contributions to the electron-transfer and H-transfer fields, as seen in the copious citations in the present volume. I am indebted to Judith Klinman, Amnon Kohen, Sharon Hammes-Schiffer and Maria-Elisabeth Michel-Beyerle for their helpful comments. The research described in this preface was supported by the National Science Foundation and the Office of Naval Research. Recent reviews and other articles are cited in the author's J. Phys. Chem. B, 2007, 111, 6643 and J. Chem. Phys., 2006, 25, Art. No. 194504, which also elaborate on several of the topics mentioned here.Attached Files
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- 55791
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- CaltechAUTHORS:20150316-125057976
- NSF
- Office of Naval Research (ONR)
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2015-03-16Created from EPrint's datestamp field
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2021-11-10Created from EPrint's last_modified field