Published August 15, 1990
| public
Journal Article
Unimolecular Reactions, Rates and Quantum State Distribution of Products
- Creators
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Marcus, R. A.
Chicago
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Abstract
Microcanonical rates and products rovibrational quantum state distributions of several unimolecular dissociations, and canonical rates of some bimolecular associations, are discussed from the viewpoint of variational Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The results are compared with the experimental data and with the very useful benchmark theory, phase space theory. A two-transition-state description is discussed for the threshold regions for the products vibrational excitations.
Additional Information
© 1990 The Royal Society. It is a pleasure to acknowledge the support of this research by the National Science Foundation, and helpful discussions with S. J. Klippenstein.Additional details
- Eprint ID
- 53266
- Resolver ID
- CaltechAUTHORS:20150107-103454609
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2015-01-07Created from EPrint's datestamp field
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2019-11-22Created from EPrint's last_modified field