Published November 17, 2014
| Supplemental Material
Journal Article
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Dioxygen Reactivity with a Ferrocene–Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane
- Creators
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Henthorn, Justin T.
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Agapie, Theodor
Chicago
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Abstract
Ferrocenes, which are typically air-stable outer-sphere single-electron transfer reagents, were found to react with dioxygen in the presence of B(C_6F_5)_3, a Lewis acid unreactive to O_2, to generate bis(borane) peroxide. Although several Group 13 peroxides have been reported, boron-supported peroxides are rare, with no structurally characterized examples of the BO_2B moiety. The synthesis of a bis(borane)-supported peroxide anion and its structural and electrochemical characterization are described.
Additional Information
© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 22, 2014. Article first published online: 22 SEP 2014. We thank Lawrence M. Henling and Dr. Michael Takase for crystallographic assistance. We are grateful to Caltech and NSF GRFP (J.T.H.) for funding.Attached Files
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Additional details
- Eprint ID
- 50134
- Resolver ID
- CaltechAUTHORS:20141001-090457258
- Caltech
- NSF Graduate Research Fellowship
- Created
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2014-10-09Created from EPrint's datestamp field
- Updated
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2021-11-02Created from EPrint's last_modified field