Published June 3, 2015
| Accepted Version
Journal Article
Open
Highly functionalized donor–acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids
Chicago
An error occurred while generating the citation.
Abstract
A series of highly substituted vinylcyclopropanes were prepared and examined as reaction partners in a palladium-catalyzed (3 + 2) cycloaddition with nitrostyrenes. Described herein are our efforts to synthesize an elusive 1,1-divinylcyclopropane by several distinct approaches, and to apply surrogates of this fragment toward the synthesis of the Melodinus alkaloids.
Additional Information
© 2014 Elsevier Ltd. Received Date: 14 August 2014; Revised Date: 28 August 2014; Accepted Date: 3 September 2014; Available online 16 September 2014. The authors wish to thank NIH-NIGMS (R01GM080269-01), Amgen, and Caltech for financial support. A.F.G.G. thanks the Natural Sciences and Engineering Research Council (NSERC) of Canada for a PGS D scholarship. R.A.C. gratefully acknowledges the support of this work provided by a fellowship from the National Cancer Institute of the National Institutes of Health under Award Number F31CA174359.Attached Files
Accepted Version - nihms627841.pdf
Files
nihms627841.pdf
Files
(707.5 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:89fbfed3b181391cef2d035553133023
|
707.5 kB | Preview Download |
Additional details
- PMCID
- PMC4479304
- Eprint ID
- 50125
- DOI
- 10.1016/j.tetlet.2014.09.016
- Resolver ID
- CaltechAUTHORS:20140930-130037903
- NIH
- R01GM080269-01
- Amgen
- Caltech
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- NIH Predoctoral Fellowship
- F31CA174359
- Created
-
2014-10-01Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field