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Published August 2014 | public
Conference Paper

Redox properties of cobalt μ4-oxo complexes [MCo_3O]^n+ incorporating redox inactive metals (M = Li^+, Zn^2+, Co^2+)

Abstract

The synthesis and reactivity of cobalt oxo cluster complexes will be presented. Using a hexapyridyl-trialkoxide ligand, a trinuclear Co complex was used as a platform for the prepn. of tetrametallic oxido cluster complexes [MCo_3O]^n+ where M = Li^+, Zn^2+, Co^2+. Reactivity of such complexes toward oxygen atom transfer reagents and their redox properties will be discussed.

Additional Information

© 2014 American Chemical Society.

Additional details

Created:
August 20, 2023
Modified:
October 17, 2023