Published August 2014
| public
Conference Paper
Catalytic cross-coupling with copper and light
- Creators
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Peters, Jonas C.
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Fu, Gregory
Chicago
Abstract
Carbon-nitrogen bond-forming reactions of amines with aryl halides to generate arylamines (anilines), mediated by a stoichiometric copper reagent at elevated temp. (>180 °C), were first described by Ullmann in 1903. Recent advances in catalytic Ullmann-type cross-couplings make these bond-forming processes powerful tools for org. synthesis. In this talk I will describe a recent collaborative effort between the Fu and Peters research groups at Caltech to develop photo-induced, copper-catalyzed C-X cross-couplings (X = N, S, O, C) as a methodolgically simple, mild approach to Ullmann-type bond constructions.
Additional Information
© 2014 American Chemical Society.Additional details
- Eprint ID
- 48375
- Resolver ID
- CaltechAUTHORS:20140812-105957073
- Created
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2014-08-12Created from EPrint's datestamp field
- Updated
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2019-10-03Created from EPrint's last_modified field