Published August 2014
| public
Conference Paper
Stabilization of mononuclear two-coordinate Fe(0) and Co(0) complexes
- Creators
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Ung, Gael
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Peters, Jonas C.
Chicago
Abstract
Low coordinate iron and cobalt complexes are sought after for their catalytic applications as well as their potential as bond activators. Most of the two-coordinate iron and cobalt species are in the formal +II oxidn. state, and are stabilized with extremely bulky X-type ligands. Formally zero-valent two-coordinate transition metal species are exceedingly rare and neither two-coordinate Fe(0) nor Co(0) complexes have been characterized to date. We will present the synthesis of neutral two-coordinate mononuclear iron and cobalt complexes using the vital cyclic (alkyl)(amino)carbenes as ligands. Their unusual properties and reactivity will also be discussed.
Additional Information
© 2014 American Chemical Society.Additional details
- Eprint ID
- 48345
- Resolver ID
- CaltechAUTHORS:20140811-150719732
- Created
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2014-08-11Created from EPrint's datestamp field
- Updated
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2020-03-09Created from EPrint's last_modified field