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Published September 2014 | Supplemental Material
Journal Article Open

Effects of Helium Implantation on the Tensile Properties and Microstructure of Ni₇₃P₂₇ Metallic Glass Nanostructures

Abstract

We report fabrication and nanomechanical tension experiments on as-fabricated and helium-implanted 130 nm diameter Ni₇₃P₂₇ metallic glass nanocylinders. The nanocylinders were fabricated by a templated electroplating process and implanted with He+ at energies of 50, 100, 150, and 200 keV to create a uniform helium concentration of 3 atom % throughout the nanocylinders. Transmission electron microscopy imaging and through-focus analysis reveal that the specimens contained 2 nm helium bubbles distributed uniformly throughout the nanocylinder volume. In situ tensile experiments indicate that helium-implanted specimens exhibit enhanced ductility as evidenced by a 2-fold increase in plastic strain over as-fabricated specimens with no sacrifice in yield and ultimate tensile strengths. This improvement in mechanical properties suggests that metallic glasses may actually exhibit a favorable response to high levels of helium implantation.

Additional Information

© 2014 American Chemical Society. Received: June 4, 2014; Revised: July 21, 2014; Published: August 1, 2014. The authors gratefully acknowledge the financial support of the U.S. Department of Energy through J.R.G.'s Early Career Research Program under Grant DE-SC0006599. Additional financial support was provided by X.W.G.'s National Defense Science and Engineering Graduate Fellowship and R.L.'s National Science Foundation Graduate Research Fellowship. This material is based upon work supported by the National Science Foundation Graduate Research Fellowship Program under Grant DGE-1144469. Any opinions, findings, and conclusions or recommendations expressed in the material are those of the authors and do not necessarily reflect the views of the National Science Foundation. The authors thank David Chen and Kelly Guan for developing the Ni−P electroplating conditions and Dongchan Jang and Carol Garland for TEM assistance. The authors also thank the Kavli Nanoscience Institute (KNI) at Caltech for support and availability of cleanroom facilities, and the Center for Integrated Nanotechnologies (CINT) user program for use of ion beam facilities at Los Alamos National Laboratory. This work was performed in part at the Center for Integrated Nanotechnologies, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science. Los Alamos National Laboratory, an affirmative action equal opportunity employer, is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract DEAC52-06NA25396.

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