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Published September 28, 2014 | Published + Supplemental Material
Journal Article Open

A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

Abstract

A new mechanism for generating C–O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C–O bond in phenol formed by the reaction of OVCl_3 with HgPh_2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

Additional Information

© 2014 The Royal Society of Chemistry. Received 24 Apr 2014, Accepted 28 Jul 2014, First published online 28 Jul 2014. This work was initiated with support from the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center, DOE DE-SC0001298, and completed with support from Chevron USA INC and from NSF (CHE-1214158).

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Supplemental Material - c4cc03067b1_si.pdf

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August 20, 2023
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