Published November 12, 2002
| Supplemental Material
Journal Article
Open
Synthesis of the (Dialkylamino)borate, [Ph_2B(CH_2NMe_2)_2]-, Affords Access to N-Chelated Rhodium(I) Zwitterions
- Creators
- Betley, Theodore A.
-
Peters, Jonas C.
Abstract
This paper reports the synthesis of the first bis(amino)borate ligand, [Ph_2B(CH_2NMe_2)_2]-, an anionic equivalent of tertiary diamines. Anionic [Ph_2B(CH_2NMe_2)_2] is an excellent bidentate ligand auxiliary and is used to prepare a series of N-chelated, zwitterionic rhodium(I) complexes.
Additional Information
© 2002 American Chemical Society. Received August 6, 2002. Publication Date (Web): November 12, 2002. We thank the NSF (Grant CHE-0132216), the ACS Petroleum Research Fund, and the Dreyfus Foundation for financial support. T.A.B. thanks the Department of Defense for a graduate research fellowship.Attached Files
Supplemental Material - ic0259336-2_s1.pdf
Supplemental Material - ic0259336-2_s2.cif
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Additional details
- Alternative title
- Synthesis of the (Dialkylamino)borate, [Ph2B(CH2NMe2)2]-, Affords Access to N-Chelated Rhodium(I) Zwitterions
- Eprint ID
- 47964
- DOI
- 10.1021/ic0259336
- Resolver ID
- CaltechAUTHORS:20140805-095114062
- CHE-0132216
- NSF
- American Chemical Society Petroleum Research Fund
- Camille and Henry Dreyfus Foundation
- Created
-
2014-08-05Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field