Published March 27, 2011
| public
Journal Article
Synthesis and reactivity of late transition metal complexes bearing a pincer-type diphosphinesulfoxide ligand
- Creators
- Suess, Daniel L. M.
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Peters, Jonas C.
Chicago
Abstract
A new pincer-type diphosphinesulfoxide ligand ("SOP_2") has been synthesized and complexed to a no. of middle and late transition metals. The central sulfoxide donor behaves as a σ donor and a Π acceptor, which has been chem. Demonstrated by the prepn. of (SOP_2)IrCl and its ability to bind dioxygen analogously to Vaska's complex. The suitability of this ligand architecture to accommodate both low-valent group 9 and 10 metal centers as well as high-valent centers with strongly Π-donating ligands trans to the sulfoxide donor will be the primary focus of discussion.
Additional Information
© 2011 American Chemical Society.Additional details
- Eprint ID
- 47784
- Resolver ID
- CaltechAUTHORS:20140801-104149023
- Created
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2014-08-01Created from EPrint's datestamp field
- Updated
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2019-11-26Created from EPrint's last_modified field