Published September 10, 2006
| public
Journal Article
Electrocatalytic hydrogen evolution with first-row metals: A bimetallic approach
- Creators
- Mendiratta, Arjun
-
Peters, Jonas C.
Chicago
Abstract
A new family of dinucleating ligands has been designed and their dicobalt complexes synthesized. The ability of these compds. to catalyze the redn. of protons to dihydrogen has been thoroughly investigated using both electrochem. and spectroscopic methods. Structure-function relationships and mechanistic proposals are presented and comparisons are made both to mononuclear analogs and to the bimetallic active site of Fe-only hydrogenase.
Additional Information
© 2006 American Chemical Society.Additional details
- Eprint ID
- 47578
- Resolver ID
- CaltechAUTHORS:20140730-080709798
- Created
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2014-07-30Created from EPrint's datestamp field
- Updated
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2019-11-26Created from EPrint's last_modified field