Published March 13, 2005
| public
Journal Article
Highly emissive, redox active amido-bridged Cu_2N_2 diamond core complexes supported by phosphine ligands
- Creators
- Harkins, Seth B.
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Peters, Jonas C.
Chicago
Abstract
A series of novel Cu_2N_2 diamond core structures supported by P_2N- ligands have been prepd. These diamond core systems exhibit reversible 1-electron redox processes between the Cu^1Cu^1, [CuCu]^+, [CuCu]^2+ states. The solid-state mol. structures of each show that minimal overall structural reorganization occurs, though minor core distortions are present. Addnl., the Cu^1Cu^1, form is highly emissive (φ > 65%, τ > 10 μs) and gives rise to interesting photoreductive chem. The magnetic, electrochem. and spectroscopic data, as well as initial reactivity studies, will be discussed.
Additional Information
© 2005 American Chemical Society.Additional details
- Alternative title
- Highly emissive, redox active amido-bridged Cu2N2 diamond core complexes supported by phosphine ligands
- Eprint ID
- 47568
- Resolver ID
- CaltechAUTHORS:20140729-145420932
- Created
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2014-07-30Created from EPrint's datestamp field
- Updated
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2019-11-26Created from EPrint's last_modified field