Published March 13, 2005
| public
Journal Article
Exploratory studies of iron and cobalt complexes supported by strong-field tripodal (phosphino)borate ligands
- Creators
- Thomas, Christine M.
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Peters, Jonas C.
Chicago
Abstract
Recent work within our lab has focused on the coordination chem. of late transition metal complexes supported by the strong-field, tripodal phosphino(borate) ligands [PhB(CH_2PPh_2)_3]- and [PhB(CH_2PiPr_2)_3]-. These platforms have been shown to stabilize a variety of metal oxidn. states and, moreover, a no. of unique coordination compds. featuring metal-nitrogen multiple bonds. With this in mind, the reactivity of low valent iron and cobalt complexes with substrates such as diazoalkanes and elemental phosphorous (P_4) will be presented and avenues to metal-phosphorous and/or metal-carbon multiple bonds will be discussed.
Additional Information
© 2005 American Chemical Society.Additional details
- Eprint ID
- 47560
- Resolver ID
- CaltechAUTHORS:20140729-130315618
- Created
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2014-07-29Created from EPrint's datestamp field
- Updated
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2019-11-26Created from EPrint's last_modified field