Published March 28, 2004
| public
Journal Article
Redox active amido-bridged Cu_2N_2 diamond core complexes supported by thioether and phosphine ligands
- Creators
- Harkins, Seth B.
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Peters, Jonas C.
Chicago
Abstract
A series of novel Cu_2N_2 diamond core structures supported by S_2N- and P_2N- ligands have been prepared. These diamond core systems exhibit a reversible 1-electron redox process between a reduced Cu^1Cu^1 and a class Ill delocalized Cu^(1.5)Cu^(1.5) state. Solid-state molecular structures have been obtained of both the oxidized and reduced forms of this system. Minimal overall structural reorganization is observed between the reduced and oxidized states, though a marked CuCu compression (-0.13 Å) does occur upon oxidation. As a result, unusually facile electron self-exchange arises. Magnetic, electrochemical and spectroscopic data, as well as their reactivity, will be discussed.
Additional Information
© 2004 American Chemical Society.Additional details
- Alternative title
- Redox active amido-bridged Cu2N2 diamond core complexes supported by thioether and phosphine ligands
- Eprint ID
- 47535
- Resolver ID
- CaltechAUTHORS:20140728-152907139
- Created
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2014-07-29Created from EPrint's datestamp field
- Updated
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2019-11-26Created from EPrint's last_modified field