Published March 26, 2000
| public
Journal Article
Silylene extrusion from silanes: Direct conversion of R2SiH2 to iridium silylene dihydride complexes
Chicago
Abstract
Silylene complexes, the silicon analogues of carbene complexes, feature three-coordinate, divalent silicon bound to a metal (R_2Si=ML_n). Significant advances in the preparation of these highly electrophilic species have been made in our laboritories over the past decade including, most recently, the preparation of the first iridium silylene complex as a zwitterion: [PhB(CH_2PPh_2)_3]lr(H)(eta-3-C_8H_(13)) + Mes_2SiH_2-[PhB(CH_2PPh_2)_3](H)_2lr=SiMes_2.
Additional Information
© 2000 American Chemical Society.Additional details
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