Published April 29, 2002
| Supplemental Material
Journal Article
Open
Base-Promoted Benzene C−H Activation Chemistry at an Amido Pincer Complex of Platinum(II)
- Creators
- Harkins, Seth B.
-
Peters, Jonas C.
Abstract
The thermally robust platinum(II) complex (BQA)Pt(OTf) undergoes benzene C−H bond activation at 150 °C but requires the presence of N^iPr_2Et. The reaction products are the phenyl complex (BQA)Pt(Ph) and a stoichiometric equivalent of [HN^iPr_2Et][OTf].
Additional Information
© 2002 American Chemical Society. Received December 7, 2001; Publication on Web 04/02/2002. We thank BP, Caltech, and the Dreyfus Foundation for financial support of this work and Larry Henling for crystallographic assistance. Members of the Bercaw group are thanked for insightful discussions.Attached Files
Supplemental Material - om011044z_s.pdf
Files
om011044z_s.pdf
Files
(795.9 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:701798bdecfe0b4207172a82c016e5f2
|
795.9 kB | Preview Download |
Additional details
- Eprint ID
- 47399
- Resolver ID
- CaltechAUTHORS:20140722-122514070
- BP
- Caltech
- Camille and Henry Dreyfus Foundation
- Created
-
2014-07-22Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field