Published January 12, 2004
| Supplemental Material
Journal Article
Open
Coordinating Anions: (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis
- Creators
- Thomas, Christine M.
-
Peters, Jonas C.
Chicago
Abstract
Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.
Additional Information
© 2004 American Chemical Society. Received August 31, 2003. The NSF (CHE-01232216) and BP have provided financial support for this work. Larry Henling and J. Christopher Thomas provided assistance with the crystallographic studies.Attached Files
Supplemental Material - ic0350234si20030831_081827.pdf
Supplemental Material - ic0350234si20030831_081910.cif
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ic0350234si20030831_081827.pdf
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Additional details
- Eprint ID
- 47392
- DOI
- 10.1021/ic0350234
- Resolver ID
- CaltechAUTHORS:20140722-104615116
- NSF
- CHE-01232216
- BP
- Created
-
2014-07-22Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field