Published July 10, 2000
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Journal Article
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Synthesis and Structure of Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. A Lithium Complex Supported by a Cp/TACN-^iPr_2 Ligand
Abstract
The new ligand (C_5H_5)CH_2CH_2(TACN-^iPr_2) (TACN-^iPr_2 = 4,7-diisopropyl-1,4,7-triaza-1-cyclononyl) has been prepared and structurally characterized as its lithium complex, Li[(C_5H_4)CH_2CH_2(TACN-^iPr_2)]. The method of preparation employed nucleophilic addition of the lithium amide complex [Li(TACN-^iPr_2)]_2 to spiro[2.4]hepta-4,6-diene. The crystal structure of [Li(TACN-^iPr_2)]_2 is also presented.
Additional Information
© 2000 American Chemical Society. Received February 15, 2000; Publication on Web 05/31/2000. We wish to thank the California Institute of Technology for its generous support of this research through a start-up grant. We would like to express our thanks to Professor John Arnold for discussing related results with us prior to publication. Finally, Mr. Matthew Allen is acknowledged for his assistance with the preparation of TACN-^iPr_2.Attached Files
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Additional details
- Eprint ID
- 47389
- DOI
- 10.1021/om000147z
- Resolver ID
- CaltechAUTHORS:20140722-095258009
- Caltech
- Created
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2014-07-22Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field