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Published December 1, 1949 | Published
Journal Article Open

The Infra-Red Spectrum and Molecular Configuration of Hydrogen Persulfide

Abstract

The infra‐red spectrum of hydrogen persulfide has been investigated in the region 1.5 to 15μ, and vibrational assignments have been made. The perpendicular band at 2μ has been studied under high resolution and a value for one of the rotational constants has been obtained. The data strongly support a chain structure for hydrogen persulfide and probably exclude cis- or trans-planar structures, but give no very definite information regarding the azimuthal angle.

Additional Information

© 1949 American Institute of Physics. Received March 25, 1949. Contribution No. 1264 from the Gates and Crellin Laboratories of Chemistry.

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