Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published June 10, 2010 | Supplemental Material + Published
Journal Article Open

Efficient luminescence from easily prepared three-coordinate copper(I) arylamidophosphines

Abstract

A series of brightly luminescent, three-coordinate copper(I) arylamidophosphine complexes have been prepared from readily available precursors in high yield. Emission maxima span 102 nm in the visible spectrum from 461 (blue) to 563 nm (yellow) while photoluminescence quantum yields range from 0.11 to 0.24 in fluid solution at room temperature.

Additional Information

This journal is © The Royal Society of Chemistry 2010. Received 13th January 2010, Accepted 30th March 2010, First published on the web 14th April 2010. This work was supported by an NSF Center for Chemical Innovation (CHE-0802907). Luminescence measurements were carried out in the laboratory of T. M. Swager with assistance from T. L. Andrews. K. J. L. gratefully acknowledges a fellowship from the MIT Energy Initiative. Electronic supplementary information (ESI) available: Synthetic procedures and characterization, absorption spectrum of 6, excitation and emission spectra, electrochemical data, and solid state structures. CCDC 766167 (1), 766168 (2), 766169 (3), 766170 (7). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c000818d

Attached Files

Published - c000818d.pdf

Supplemental Material - c000818d__1_.pdf

Supplemental Material - c000818d.txt

Files

c000818d__1_.pdf
Files (2.7 MB)
Name Size Download all
md5:5eaeacd3cdd9889068f3c5ed8afb454c
1.4 MB Preview Download
md5:6e7d111056d55836394b5e9984a0b3c7
1.2 MB Preview Download
md5:cda3d99be07cc776ebbc8318a715387f
97.9 kB Preview Download

Additional details

Created:
August 19, 2023
Modified:
October 26, 2023