Published June 10, 2010
| Supplemental Material + Published
Journal Article
Open
Efficient luminescence from easily prepared three-coordinate copper(I) arylamidophosphines
- Creators
- Lotito, Kenneth J.
-
Peters, Jonas C.
Chicago
Abstract
A series of brightly luminescent, three-coordinate copper(I) arylamidophosphine complexes have been prepared from readily available precursors in high yield. Emission maxima span 102 nm in the visible spectrum from 461 (blue) to 563 nm (yellow) while photoluminescence quantum yields range from 0.11 to 0.24 in fluid solution at room temperature.
Additional Information
This journal is © The Royal Society of Chemistry 2010. Received 13th January 2010, Accepted 30th March 2010, First published on the web 14th April 2010. This work was supported by an NSF Center for Chemical Innovation (CHE-0802907). Luminescence measurements were carried out in the laboratory of T. M. Swager with assistance from T. L. Andrews. K. J. L. gratefully acknowledges a fellowship from the MIT Energy Initiative. Electronic supplementary information (ESI) available: Synthetic procedures and characterization, absorption spectrum of 6, excitation and emission spectra, electrochemical data, and solid state structures. CCDC 766167 (1), 766168 (2), 766169 (3), 766170 (7). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c000818dAttached Files
Published - c000818d.pdf
Supplemental Material - c000818d__1_.pdf
Supplemental Material - c000818d.txt
Files
c000818d__1_.pdf
Additional details
- Eprint ID
- 44651
- Resolver ID
- CaltechAUTHORS:20140403-160228002
- NSF Center for Chemical Innovation
- CHE-0802907
- MIT Energy Initiative
- Created
-
2014-04-04Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Caltech groups
- CCI Solar Fuels
- Other Numbering System Name
- CCDC
- Other Numbering System Identifier
- 766170