Published November 28, 2009
| Supplemental Material + Published
Journal Article
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Redox rich dicobalt macrocycles as templates for multi-electron transformations
Abstract
Pyridazine-templated dicobalt macrocycles reversibly support five oxidation states with unusually positive Co^(II)/Co^I redox couples, and are also active proton reduction electrocatalysts.
Additional Information
This journal is © The Royal Society of Chemistry 2009. Received 13 Jul 2009, Accepted 17 Sep 2009, First published online 06 Oct 2009. This work was generously supported by BP and an NSF Center for Chemical Innovation grant (Grant CHE-0802907). We thank Dr Yunho Lee and Dr Sebastian Stoian for EPR assistance, and Dr Bruce Brunschwig for helpful discussions. Electronic supplementary information (ESI) available: Complete experimental details and crystal structures. CCDC 740044–740052. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b913946jAttached Files
Published - b913946j.pdf
Supplemental Material - b913946j__1_.pdf
Supplemental Material - b913946j.txt
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b913946j.txt
Additional details
- Eprint ID
- 44646
- Resolver ID
- CaltechAUTHORS:20140403-151953405
- BP
- CHE-0802907
- NSF Center for Chemical Innovation
- Created
-
2014-04-03Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Caltech groups
- CCI Solar Fuels