Published 1962
| Published
Journal Article
Open
Nuclear Magnetic Resonance Spectroscopy. Structure and Dynamic Character of Allylic Grignard Reagents
Chicago
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Abstract
Studies have been made of the nuclear magnetic resonance spectra of several allylic Grignard reagents. The Grignard reagent prepared from γ,γ-dimethylallyl bromide appears best formulated as an equilibrium mixture of γ,γ-dimethylallylmagnesium bromide and α,α-dimethylallylmagnesium bromide, in which the former is the major component. The rate of interconversion of the allylic isomers is rapid on the n.m.r. time scale at room temperature, but slow at -40°.
Additional Information
© 1962 Royal Society of Chemistry. Received 1st June, 1962. Supported in part by the Office of Naval Research.Attached Files
Published - WHIdfs62.pdf
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Additional details
- Eprint ID
- 42948
- Resolver ID
- CaltechAUTHORS:20131211-095900745
- Office of Naval Research (ONR)
- Created
-
2013-12-11Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2847