Published September 6, 2013
| Supplemental Material + Published
Journal Article
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Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene
Abstract
A catalyst for the oligomerization of 1-hexene, generated by the activation of a benzimidazolylidene zirconium dibenzyl complex, switches to a polymerization catalyst on addition of a trialkylphosphine.
Additional Information
© 2013 Royal Society of Chemistry. Received 26th August 2013, Accepted 1st September 2013. First published online 06 Sep 2013. This work was supported by the USDOE Office of Basic Energy Sciences (grant no. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094). We thank Dr Mona Shahgholi for the MALDITOF analysis.Attached Files
Published - Despagnet_2013p15544.pdf
Supplemental Material - c3dt52342j.pdf
Supplemental Material - c3dt52342j.txt
Files
c3dt52342j.txt
Additional details
- Eprint ID
- 42819
- Resolver ID
- CaltechAUTHORS:20131204-094018041
- DE-FG03-85ER13431
- Department of Energy (DOE)
- CHE-0639094
- NSF
- Created
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2013-12-04Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field