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Published December 24, 2007 | public
Journal Article

Entropy Evaluation of the Superprotonic Phase of CsHSO_4: Pauling's Ice Rules Adjusted for Systems Containing Disordered Hydrogen-Bonded Tetrahedra

Abstract

The entropy of the superprotonic transition (phase II → phase I) of CsHSO₄ is evaluated both experimentally and theoretically. Calorimetric measurements reveal a value of 14.75(22) J mol⁻¹ K⁻¹. Under the assumption that the entropy is entirely configurational, arising from both sulfate group orientational disorder and disorder in the hydrogen-bond network, we evaluated several structural models of CsHSO₄ for their consistency with the measured entropy. For a structure in which hydrogen-bond disorder is independent of sulfate-group orientational disorder, simple methods of calculating the number of structural configurations are inadequate. Thus, the configurational entropy of the superprotonic, disordered phase of CsHSO₄ is evaluated using an approach similar to that employed by Pauling to describe the residual entropy of ice at 0 K. Analogous to ice and the so-called ice rules, superprotonic CsHSO₄ is assumed to obey a set of structural rules. Key among these are that there is only one proton per sulfate tetrahedron and only one proton per hydrogen bond. Defects are argued to make a negligible contribution to the transition entropy. The transition entropy obtained from this model, 14.9 J mol⁻¹ K⁻¹, is in excellent agreement with the measured value. Such a match between theoretical and experimental values suggests that of all published Phase I structures, the structure proposed by Jirak² more correctly describes the arrangements of the sulfate tetrahedra and protons attached to them. The assumption of a low defect concentration implies that the jump in proton conductivity at the transition is due to an increase in the mobility of charge carriers rather than their concentration.

Additional Information

Copyright © 2007 American Chemical Society. Received August 31, 2006. Revised Manuscript Received October 26, 2006. Publication Date (Web): December 24, 2006. CM062070W. The authors thank Dr. Jeff Snyder and Dr. Dane Boysen for insightful discussions. This work has been supported by the National Science Foundation, DMR-0435221, and by the Donors of the American Chemical Society Petroleum Research Fund.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023