Published October 18, 2013
| Supplemental Material
Journal Article
Open
Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst
Chicago
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Abstract
Breaking the rules: Reversal of the high Markovnikov selectivity of Wacker-type oxidations was accomplished using a nitrite co-catalyst. Unbiased aliphatic alkenes can be oxidized with high yield and aldehyde selectivity, and several functional groups are tolerated. ^(18)O-labeling experiments indicate that the aldehydic O atom is derived from the nitrite salt.
Additional Information
© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Issue published online: 14 Oct 2013; Article first published online: 13 Sep 2013; Manuscript Received: 2 Aug 2013. We thank Scott Virgil for technical assistance. We acknowledge KAUST, KFUPM, and NSF for funding and the SNSF for a fellowship to B.M.Attached Files
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Additional details
- Eprint ID
- 42230
- Resolver ID
- CaltechAUTHORS:20131104-143606168
- King Abdullah University of Science and Technology (KAUST)
- King Fahd University of Petroleum and Minerals (KFUPM)
- NSF
- Swiss National Science Foundation (SNSF)
- Created
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2013-11-04Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field