Published June 19, 2013
| Accepted Version + Supplemental Material
Journal Article
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Synthesis of Highly Cis, Syndiotactic Polymers via Ring-Opening Metathesis Polymerization Using Ruthenium Metathesis Catalysts
Chicago
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Abstract
The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
Additional Information
© 2013 American Chemical Society. Received: June 4, 2013; Published: June 19, 2013.Attached Files
Accepted Version - nihms497126.pdf
Supplemental Material - Supporting_info.pdf
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Supporting_info.pdf
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Additional details
- PMCID
- PMC3773019
- Eprint ID
- 41430
- Resolver ID
- CaltechAUTHORS:20130919-155320130
- NIH
- R01-GM031332
- NSF
- CHE-1212767
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- NIH
- RR027690
- Created
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2013-09-30Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field