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Published 1997 | public
Journal Article

Homolytic cycloaddition of dithiols to alkynes leading to sulfur-containing heterocycles and crown thioethers: new comments to the mechanism

Abstract

Multicenter three-electron (3e-2c) S-S bond formation can be employed to explain the cyclization in the homolytic addn. of α,ω-thiols to alkynes.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023