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Published July 30, 1969 | Published
Journal Article Open

A Dihydroxo-Bridged Ferric Dimer

Abstract

Recent investigations have produced a large number of dimeric complexes containing the oxo-bridged structural unit Fe_2O^(4+). Here we report the isolation and characterization of [Fe (pic)_2OH]_2 which apparently is the first example of a crystalline iron(III) dimer which utilizes dihydroxo bridging in its coordination structure.

Additional Information

© 1969 American Chemical Society. Research at the California Institute of Technology was supported by the National Science Foundation; research at Rutgers University was supported by the Petroleum Research Fund and the Rutgers University Research Fund. We thank Professors R. Herber and J. Potenza for the Mössbauer and X-ray crystallographic measurements.

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August 23, 2023
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October 23, 2023