Equilibration timescale of atmospheric secondary organic aerosol partitioning

Abstract

[1] Secondary organic aerosol (SOA) formed from partitioning of oxidation products of anthropogenic and biogenic volatile organic compounds (VOCs) accounts for a substantial portion of atmospheric particulate matter. In describing SOA formation, it is generally assumed that VOC oxidation products rapidly adopt gas-aerosol equilibrium. Here we estimate the equilibration timescale, τ_(eq), of SOA gas-particle partitioning using a state-of-the-art kinetic flux model. Τ_(eq) is found to be of order seconds to minutes for partitioning of relatively high volatility organic compounds into liquid particles, thereby adhering to equilibrium gas-particle partitioning. However, τ_(eq) increases to hours or days for organic aerosol associated with semi-solid particles, low volatility, large particle size, and low mass loadings. Instantaneous equilibrium partitioning may lead to substantial overestimation of particle mass concentration and underestimation of gas-phase concentration.

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