Published June 14, 2010
| Erratum + Published
Journal Article
Open
Coriolis coupling as a source of non-RRKM effects in ozone molecule: Lifetime statistics of vibrationally excited ozone molecules
- Creators
- Kryvohuz, M.
-
Marcus, R. A.
Chicago
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Abstract
A theory that describes the non-RRKM (non-Rice-Ramsperger-Kassel-Marcus) effects in the lifetime statistics of activated ozone molecules is derived. The non-RRKM effects are shown to originate due to the diffusive energy exchange between vibrational and rotational degrees of freedom in ozone molecule. The lifetime statistics is found to be intramolecular diffusion controlled at long times. The theoretical results are in good agreement with the direct MD simulations of lifetime statistics.
Additional Information
© 2010 American Institute of Physics. Received 27 October 2009; accepted 27 April 2010; published online 8 June 2010. We are pleased to acknowledge the support of this research by the Glanville Fellowship to M.K. and by an NSF grant to R.A.M.Attached Files
Published - JChemPhys_132_224305.pdf
Erratum - JChemPhys_137_159902.pdf
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Additional details
- Eprint ID
- 35725
- Resolver ID
- CaltechAUTHORS:20121129-095751831
- Glanville Fellowship
- NSF
- Created
-
2012-11-29Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field