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Published February 1, 1989 | Published
Journal Article Open

Experimental determination of dipole moments for molecular ions: Improved measurements for ArH^+

Abstract

An improved value for the dipole moment of ArH^+ has been obtained from new measurements of the rotational g factors of ArH^+ and ArD^+ made with tunable far‐IR laser spectroscopy. Systematic errors present in earlier measurements have been eliminated. The new result (μ=3.0±0.6 D) is slightly higher than the ab initio value of Rosmus (2.2 D) at the 2σ limits of precision.

Additional Information

© 1989 American Institute of Physics. Received 18 August 1988; accepted 19 October 1988. This work was supported by the National Science Foundation (Grant No. CHE-12296).

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