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Published March 1, 1962 | Published
Journal Article Open

On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes

Abstract

The visible absorption spectra of the ions [Fe(CN)_(5)NO]^(2-), [Mn(CN)_(5)NO]^(3—), and [Cr(CN)_(5)NO]^(3—) are interpreted using a crystal field level scheme of C_(4v) symmetry. Assuming a strong axial compression to be present a self‐consistent assignment is obtained for both the 3d^5 and 3d^6 electronic configurations.

Additional Information

© 1962 American Institute of Physics. Received 24 August 1961. National Science Foundation Postdoctoral Fellow, 1960-61.

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August 19, 2023
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