Published 1972
| Published
Journal Article
Open
Deactivation of biacetyl triplets by cyanocobaltate(III) complexes
Chicago
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Abstract
The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–, N_(3)^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.
Additional Information
© 1972 Royal Society of Chemistry. Received: 12 June 1972; Com. 999. This research was supported by the Directorate of Chemical Sciences, Air Force Office of Scientific Research, and the Army Research Office, Durham.Attached Files
Published - WRIjcscc72.pdf
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Additional details
- Eprint ID
- 33178
- Resolver ID
- CaltechAUTHORS:20120814-131933097
- Air Force Office of Scientific Research (AFOSR) Directorate of Chemical Sciences
- Army Research Office (ARO) Durham
- Created
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2012-08-14Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field