7-Azabicyclo[2.2.1]heptane N-Imide as an Intermediate in the Thermal Decomposition of N-Amino-7-Azabicyclo[2.2.1]heptane and the Corresponding Benzenesulphonamide

Abstract

An intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide derivative, whose structure is consistent with the formulation 7-azabicyclo[2.2.1]heptane N-imide, affords on thermal fragmentation the hydrocarbon products hexa-1,5-diene, bicyclo[2.2.0]hexane, and cyclohexene and does not rearrange to the corresponding stable 2,3-diazabicyclo[2.2.2]oct-2-ene isomer.

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