Published July 15, 1970
| Published
Journal Article
Open
Relation between State‐Selected or State‐Averaged Cross Sections of Endothermic Reactions and Rate Constants of Exothermic Reactions. Application of Bimolecular Microcanonical Activated Complex Theory
- Creators
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Marcus, R. A.
Chicago
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Abstract
An expression is derived relating state‐selected or state‐averaged molecular beam reaction cross sections of endothermic reactions to observed rate constants for the inverse (exothermic) reactions. An approximation of Anlauf, Maylotte, Polanyi, and Bernstein is used, together with bimolecular microcanonical activated complex theory [R. A. Marcus, J. Chem. Phys. 45, 2138 (1966)].
Additional Information
© 1970 American Institute of Physics. Received 16 February 1970. I am particularly indebted to J. C. Polanyi and R. B. Bernstein for their very helpful correspondence and suggestions, and for transmitting to me their results in advance of publication. It is also a pleasure to acknowledge helpful discussions with Dr. Wing Wong of this laboratory. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. This research was also supported by a grant from the National Science Foundation.Attached Files
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Additional details
- Eprint ID
- 32891
- Resolver ID
- CaltechAUTHORS:20120802-133824399
- American Chemical Society Petroleum Research Fund
- NSF
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2012-08-02Created from EPrint's datestamp field
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2021-11-09Created from EPrint's last_modified field