Published August 1978
| Published
Journal Article
Open
Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2'-Bipyridine Complexes
- Creators
- Margel, Shlomo
- Anson, Fred C.
Chicago
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Abstract
The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′‐bipyridine. A prominent reaction product of the catalyzed reduction is 1,5‐hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt‐2,2′‐bipyridine complexes.
Additional Information
© 1978 Electrochemical Society. This work was supported by the National Science Foundation. A Chaim Weizmann Fellowship supplied partial support for S.M. Manuscript submitted Sept. 12, 1977; revised manuscript received ca. March 25, 1978. Any discussion of this paper will appear in a Discussion Section to be published in the June 1979 Journal. All discussions for the June 1979 Discussion Section should be submitted by Feb. 1, 1979.Attached Files
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Additional details
- Eprint ID
- 32859
- Resolver ID
- CaltechAUTHORS:20120802-082030036
- NSF
- Chaim Weizmann Fellowship
- Created
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2012-08-02Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field