Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published August 1978 | Published
Journal Article Open

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2'-Bipyridine Complexes

Abstract

The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′‐bipyridine. A prominent reaction product of the catalyzed reduction is 1,5‐hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt‐2,2′‐bipyridine complexes.

Additional Information

© 1978 Electrochemical Society. This work was supported by the National Science Foundation. A Chaim Weizmann Fellowship supplied partial support for S.M. Manuscript submitted Sept. 12, 1977; revised manuscript received ca. March 25, 1978. Any discussion of this paper will appear in a Discussion Section to be published in the June 1979 Journal. All discussions for the June 1979 Discussion Section should be submitted by Feb. 1, 1979.

Attached Files

Published - MARjes78b.pdf

Files

MARjes78b.pdf
Files (367.7 kB)
Name Size Download all
md5:2c00523f1a8269fdbf18b7e6f9077ded
367.7 kB Preview Download

Additional details

Created:
September 14, 2023
Modified:
October 23, 2023