Published October 1933
| Published
Journal Article
Open
The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems
- Creators
- Pauling, Linus
- Sherman, J.
Chicago
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Abstract
The quantum‐mechanical treatment previously applied to benzene, naphthalene, and the hydrocarbon free radicals is used in the calculation of extra resonance energy of conjugation in systems of double bonds, the dihydronaphthalenes and dihydroanthracenes, phenylethylene, stilbene, isostilbene, triphenylethylene, tetraphenylethylene, biphenyl, o, m, and p‐diphenylbenzene, and 1,3,5‐triphenylbenzene. The calculated values, which are in approximate agreement with empirical values from thermochemical data, are used in the discussion of chemical properties and in the formulation of rules regarding conjugation in overlapping systems.
Additional Information
© 1933 American Institute of Physics. Received 3 July 1933. Contribution No. 370. We are indebted to Professor G. E. K. Branch and to Dr. G. W. Wheland for pointing this out to us.Attached Files
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Additional details
- Eprint ID
- 32852
- Resolver ID
- CaltechAUTHORS:20120801-164037906
- Created
-
2012-08-02Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates Chemical Laboratory
- Other Numbering System Identifier
- 370