Published 1977
| Published
Journal Article
Open
Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron
Abstract
Evidence for a 1.2-shift mechanism of the 1-5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the ^(13)C n.m.r. chemical shifts of the C_(7)H_(7) ring. A low-temperature rocking motion of both rings can be frozen out at -70 °C.
Additional Information
© 1977 Royal Society of Chemistry. Received 4th August, 1976. We thank Drs. Mark, Bausch, and Grevels at the Institut fur Strahlenchemie for helpful discussions. One of us (R. H. G.) thanks the Alexander von Humboldt Stiftung for a research fellowship.Attached Files
Published - BLAjcsdt77.pdf
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Additional details
- Eprint ID
- 32816
- Resolver ID
- CaltechAUTHORS:20120731-104952634
- Alexander von Humboldt Stiftung
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2012-08-01Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field