Published December 1984
| Published
Journal Article
Open
Three-photon resonant four-photon ionization of H_2 via the C^1 ∏_u state
- Creators
- Dixit, S. N.
- Lynch, D. L.
- McKoy, V.
Chicago
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Abstract
Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant four-photon ionization of H_2 via the C^1Π_u state. Energy and internuclear distance dependences of the boundfree electronic transition matrix element are explicitly included to estimate deviations from the Franck-Condon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain.
Additional Information
© 1984 The American Physical Society. Received 4 September 1984; published in the issue dated December 1984. The authors wish to thank R. J. Cave and V. K. Babamov for providing us with the finite element program used for calculating the vibrational wave functions. This research was supported by the National Science Foundation under Grant No. CHE-8218166. The research reported in this paper made use of the Dreyfus-National Science Foundation Theoretical Chemistry Computer which was funded through grants from the Camille & Henry Dreyfus Foundation, the National Science Foundation (Grant No. CHE-7820235), and the Sloan Fund of the California Institute of Technology.Attached Files
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Additional details
- Eprint ID
- 32224
- Resolver ID
- CaltechAUTHORS:20120702-092209500
- NSF
- CHE-8218166
- Camille and Henry Dreyfus Foundation
- NSF
- CHE-7820235
- Caltech Sloan Fund
- Created
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2012-07-02Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field