Published 1987
| Published
Journal Article
Open
Metal-Oxo Photo-oxidants, Photochemistry and Photophysics of trans-[Os^(VI)(tmc)(O)_2]^(2+)(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os^(VI)(CN)_4(O)_2]^(2-)
Chicago
An error occurred while generating the citation.
Abstract
trans-[Os^(VI)(tmc)(O)_2]^(2+)(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os^(VI)(CN)_4(O)_2]^(2-) are emissive in the solid state and in fluid solutions at room temperature (τ~ 1.0–1.5 µs); the (^3)E_g state of trans-[Os^(VI)(tmc)(O)_2]^(2+) is a powerful one-electron oxidant {[Os^(VI)(O)_2]^(2+) + e^– → [Os^V (O)_2]+, E^0_f > 2.0 V vs. normal hydrogen electrode} in aqueous solution, reacting with PPh3 and ((PhCH_2)_2)S to give O=PPh_3 and ((PhCH_2)_2)S=O, respectively.
Additional Information
© 1987 Royal Society of Chemistry. Received 11th February 1987; Com. 183. We thank Dr. Janet L. Marshall for experimental assistance. Support from the Croucher Foundation (C. M. C. and V. W.-W. Y.) and National Science Foundation Grant CHE84-19828 (H. B. G.) is gratefully acknowledged. This is contribution No. 7573 from the Arthur Amos Noyes Laboratory. V. W.-W. Y. is a Croucher Foundation and Li Po Chun Scholar.Attached Files
Published - CHEjcscc87.pdf
Files
CHEjcscc87.pdf
Files
(282.5 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:b085902888d1fcb546b5a53ddd4bf31c
|
282.5 kB | Preview Download |
Additional details
- Eprint ID
- 32135
- Resolver ID
- CaltechAUTHORS:20120627-100742357
- Croucher Foundation
- NSF
- CHE-84-19828
- Created
-
2012-06-27Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory
- Other Numbering System Identifier
- 7573