Published March 26, 2012
| Supplemental Material
Journal Article
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Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic
Abstract
An efficient ligand combination: A new bis(diphosphine) nickel(II) complex (see picture) is described. A ΔG° value of 0.84 kcal mol^(−1) for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displayed reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, which are characteristic for hydrogenase enzymes.
Additional Information
© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: December 1, 2011. Published online: February 14, 2012. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U. S. Department of Energy.Attached Files
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Additional details
- Eprint ID
- 30267
- DOI
- 10.1002/anie.201108461
- Resolver ID
- CaltechAUTHORS:20120424-073455565
- Department of Energy (DOE)
- Created
-
2012-04-24Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field