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Published December 22, 2011 | Published
Journal Article Open

Solid State NMR Characterization of Complex Metal Hydrides systems for Hydrogen Storage Applications

Abstract

Solid state NMR is widely applied in studies of solid state chemistries for hydrogen storage reactions. Use of ^(11)B MAS NMR in studies of metal borohydrides (BH_4) is mainly focused, revisiting the issue of dodecaborane formation and observation of ^(11)B{^1H} Nuclear Overhauser Effect.

Additional Information

© 2010 Journal of Analytical Science & Technology. Published online 2011 December 22. Authors thank Dr. V. Stavila at Sandia National Laboratory for providing many borohydrides materials. This research was supported by the U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, through the Hydrogen, Fuel Cells & Infrastructure Technologies Program under contract numbers DE-AI-01-05EE11105 (JPL-Caltech). The NMR facility at Caltech was supported by the National Science Foundation (NSF) under Grant Number 9724240 and partially supported by the MRSEC Program of the NSF under Award Number DMR-520565.

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August 22, 2023
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