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Published October 1995 | Published
Journal Article Open

High-Resolution Photoelectron Spectroscopy of Molecules

Abstract

Rotationally resolved photoelectron spectra can provide significant insight into the underlying dynamics of molecular photoionization. Here, we discuss and compare results of recent theoretical studies of rotationally resolved photoelectron spectra with measurements for molecules such as HBr, OH, NO, N_2, CO, H_2O, H_2CO, and CH_3. These studies reveal the rich dynamics of quantum-state-specific studies of molecular photoionization and provide a robust description of key spectral features resulting from Cooper minima, autoionization, alignment, partial-wave mixing, and interference in related experimental studies.

Additional Information

© 1995 Annual reviews, Inc. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the US Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/116 Supercomputer.

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August 20, 2023
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