Published January 2, 2012
| Supplemental Material
Journal Article
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A Homologous Series of Cobalt, Rhodium, and Iridium Metalloradicals
- Creators
- Takaoka, Ayumi
-
Peters, Jonas C.
Chicago
Abstract
We herein present a series of d7 trimethylphosphine complexes of group 9 metals that are chelated by the tripodal tetradentate tris(phosphino)silyl ligand [SiP^(iPr)_3]H ([SiP^(iPr)_3] = (2_(-i)Pr_2PC_6H_4)_3Si^–). Both electron paramagnetic resonance (EPR) simulations and density functional theory (DFT) calculations indicate largely metalloradical character. These complexes provide a rare opportunity to compare the properties between the low-valent metalloradicals of the second- and third-row transition metals with the corresponding first-row analogues.
Additional Information
© 2011 American Chemical Society. Received: September 23, 2011. Publication Date (Web): December 1, 2011. This work was supported by the NSF (Grant CHE-0750234). Charlene Tsay and Larry Henling are acknowledged for crystallographic assistance.Attached Files
Supplemental Material - ic202079r_si_001.pdf
Supplemental Material - ic202079r_si_002.cif
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Additional details
- Eprint ID
- 29275
- DOI
- 10.1021/ic202079r
- Resolver ID
- CaltechAUTHORS:20120214-104203697
- NSF
- CHE-0750234
- Created
-
2012-02-14Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field