Published December 15, 2011
| Supplemental Material
Journal Article
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H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex
Chicago
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Abstract
A PNP-pincer iridium dihydride performs the H/D exchange between aromatic substrates and tertiary hydrosilanes and D_(2)O or C_(6)D_(6). Complete incorporation of deuterium into sterically accessible C_(ar)–H and Si–H bonds was observed at a moderate temperature of 80 °C.
Additional Information
© 2011 American Chemical Society. Received: October 28, 2011; Published: December 15, 2011. Generous financial support of this research was provided by BP (MC2 initiative). A.F. thanks the Swiss National Science Foundation for a postdoctoral fellowship.Attached Files
Supplemental Material - om201049p_si_001.pdf
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Additional details
- Eprint ID
- 29247
- DOI
- 10.1021/om201049p
- Resolver ID
- CaltechAUTHORS:20120210-151229549
- BP MC2 program
- Swiss National Science Foundation (SNSF)
- Created
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2012-02-10Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field